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selenium


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What is the health risk of too much selenium?

There is a moderate to high health risk of too much selenium. High blood levels of selenium can result in a condition called selenosis (42). Symptoms include gastrointestinal upsets, hair loss, white blotchy nails, and mild nerve damage. Selenium toxicity is rare in the United States and the few reported cases have been associated with industrial accidents and a manufacturing error that led to an excessively high dose of selenium in a supplement (43, 44). The Institute of Medicine has set a tolerable upper intake level for selenium at 400 micrograms per day for adults to prevent the risk of developing selenosis. "Tolerable upper intake levels represent the maximum intake of a nutrient that is likely to pose no risk of adverse health effects in almost al individuals in the general population" (9).

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Production

Selenium is found in a few rare minerals such as crooksite and clausthalite. In years past it has been obtained from flue dusts remaining from processing copper sulfide ores, but the anode metal from electrolytic copper refineries now provide the source of most of the world's selenium. Selenium is recovered by roasting the mud with soda or sulfuric acid, or by smelting them with soda and niter.

 

Properties

Selenium exists in several allotropic forms, although three are generally recognized. Selenium can be prepared with either an amorphous or a crystalline structure. The color of amorphous selenium is either red (in powder form) or black (in vitreous form). Crystalline monoclinic selenium is a deep red; crystalline hexagonal selenium, the most stable variety, is a metallic gray.

 

Selenium exhibits both photovoltaic action, where light is converted directly into electricity, and photoconductive action, where the electrical resistance decreases with increased illumination. These properties make selenium useful in the production of photocells and exposure meters for photographic use, as well as solar cells. Selenium is also able to convert a.c. electricity to d.c., and is extensively used in rectifiers. Below its melting point, selenium is a p-type semiconductor and has many uses in electronic and solid-state applications.

 

Elemental selenium has been said to be practically nontoxic and is considered to be an essential trace element; however, hydrogen selenide and other selenium compounds are extremely toxic, and resemble arsenic in their physiological reactions.

 

Isotopes

Naturally selenium contains six stable isotopes. Fifteen other isotopes have been characterized. The element is a member of the sulfur family and resembles sulfur both in its various forms and in its compounds.

 

Uses

Selenium is used in Xerography for reproducing and copying documents, letters, etc. It is used by the glass industry to decolorize glass and to make ruby-colored glasses and enamels. It is also used as a photographic toner, and as an additive to stainless steel.

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